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The Development Of Ammonium Nitrate

Moreover, the emission of SO2, NH3 no in the atmosphere and particular subject of the secondary compound can form also ammonium nitrate. At room temperatures and standard pressure, the ammonium nitrate looks like white crystalline solid. The three figures below show the structure formulation, and ball-stick style of the crystal structure of ammonium nitrate. Ammonium-nitrate-xtal-3D-balls-A. png

Marketing the ammonium nitrate as fertilizer became famous worldwide since 1920's. Compared to the market began to become low in 2001 and 2002 due to the security matter that followed in September 2001 disorders on the planet Trade Center which made it very difficult to produce, transport and deal with ammonium nitrate. From then on, because of the changes that accrued in agricultural subsidy plans, urea has become the main compound. It is because urea has miner protection issues, higher nitrogen fertilizer content, and it is less expensive to manufacture. In 2004, the intake of ammonium nitrate began to improve.

The ammonium nitrate is concentrated therefore the amount of ammonium nitrate present is more than in a given level of solvent such as drinking water, NH3 and HNO3. This technique is done within an evaporator. The give food to go into the evaporator reservoir which is recognized with the re-boiler heating exchanger. The heat exchanger re-boiled the ammonium nitrate solution before solvents such as H2O, NH3 and HNO3 evaporated departing a more concentrated solution called melt ammonium nitrate. Usually the amount of melt ammonium nitrate melt resulting from the evaporator is 95% to 99. 8%. In addition, the evaporated solvent will be recycled back to the CSTR.

Additives such as magnesium oxide or magnesium nitrate which they are not trusted are sometimes put into the melt ammonium nitrate for many reasons. Among the reasons is to improve the crystalline transition heat of the ultimate ammonium nitrate sound product. Furthermore, they are used to reduce the caking by removing water or any other liquids, and to reduce the freezing point of molten ammonium nitrate to allow solidification to occur at a minimal heat. The additive and the molten ammonium nitrate are mixed in a static mixer.

The most common process to produce solid ammonium nitrate with the spherical condition is prilling process. A prill tower is utilized to produce the prills of sound ammonium nitrate. At the top of the prill tower, the focused melt of ammonium nitrate melt is sprayed, and on the bottom of the prill tower, an air is growing by a blower. The slipping droplets of ammonium nitrate is cooled and solidified into a spherical prills when they are face to a increasing air.

Sometime the finish products have low density prills due to the attention of the molten ammonium nitrate. The low density prills have significantly more porous than high thickness prills. Therefore, the prills will absorb dampness content easier, and could cause lights and product deterioration. Drying process by vaporization must remove water or any other liquid from the stable ammonium nitrate prills. In a static bed tower, the sturdy prills are positioned there and from underneath of the tower, a hot air is approved through the sturdy prills.

The desired end product is spherical ammonium nitrate stable. However, the stable product may produce in variety of sizes. A display screen process is needed to check consistently the sizes of the sturdy product to acquire only the required size. The off size prills are recycled back again to the evaporation process. The proper size prills send to a chilling process, where it cools down the finish product for further operations.

Coating process is required to protect the merchandise from agglomeration during storage area and shipment. However, it is sometimes not needed. It is because the additives which were added before was melted before solidification. Therefore, there is no need to coat the merchandise with clays or diatomaceous globe for product safety.

Finally, the finish products of ammonium nitrate sturdy prills are constructed. Therefore, there are prepared for storage area or shipment by bulk or totes.

2. Production of granulated solid ammonium nitrate

Processing granules solid ammonium nitrate is equivalent to the first production of prills of sturdy ammonium nitrate. However, this time around rather than using prill tower, it uses rotary drum. This occurred by spraying concentrated ammonium nitrate in a revolving cylindrical drum onto small and fine contaminants of ammonium nitrate. As particular rotate in the rotary drum, layers of NH4NO3 are added to allergens which form granules. The NH4NO3 sturdy will than goes to the scanner. The ammonium nitrate granules are cooled down to avoid lamps. The under-size granules are smashed and recycled back again to the rotary drum as allergens. Alternatively, the oversize granules are dissolved and recycled back again to the answer process.

3. Ammonium nitrate solution process:

Ammonia gas NH3 and nitric acid solution HNO3 is added to a neutralization reactor. This technique is an exothermic neutralization response which produced ammonium nitrate solution with heavy steam. Therefore, the reactor which used is coat continues stirred container reactor the producing heavy steam which is vapor water, ammonia, and nitric acid is send to the ammonium nitrate scrubber to eliminate it from the neutralization reactor. The steam can be purified or can be condensed than purified. In addition, the vapor can be used in the evaporator to concentrate ammonium nitrate solution or a pre heating unit. . The producing solution is send to arbitrary tank following the solution is cooled. Finally the product is shipped to other plants for further control. The picture below shows the creation of ammonium nitrate solution.

Process selection:

The most crucial target in producing ammonium nitrate is to enhance the properties of agriculture throughout the world as a fertilizer. It enhances the development of the plants, gives diet, and helps it be healthy and free from diseases. It really is cheap and available in agriculture stores. It can even be found in explosive, but it is very dangerous and risky. It affects the public safety in the country. Therefore, production of spherical sound ammonium nitrate process is best selection than others for many factors.

Around 60% in america and in other Europe companies produced sturdy ammonium nitrate NH4NO3 as a fertilizer. Additionally, granulation approach is old technique and it requires more complicated crops and a number of machines such as revolving drums, fluidized mattresses and more. Presently, there are no crops in Europe using this system any longer. Nowadays, most fertilizers companies use prill technique for the development of sturdy ammonium nitrate.


In short, the creation of ammonium nitrate was done with the addition of ammonia gas and nitric acid solution. The creation of ammonium nitrate handed down through three main unit operations, which they are neutralization, evaporation and solidification. The choice of the ultimate product was influenced by the commercial subject. Substance and physical properties ammonium nitrate shows how it could be used in professional market. It could be used typically in agriculture and as explosive agent. The purpose of the procedure was to produce a spherical stable ammonium nitrate as a fertilizer to help enhance the agriculture market. The prill tower was used instead of rotary drum to get the required end product. Some diagrams such as block move diagram, process move diagram and Aspen Hysys diagram was drown to shows the movement of the ammonium nitrate production.

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